its called Kaichō wa Maid-sama! Which translates into The Student Council President is a Maid!
My info about the series:
Its an series based around the high school a nd the president of a class keeping the males in line , which ends up becoming a maid at a maid cafe to earn more money to help her family since her dad ran out with huge debts.
Info from Wiki:
The story is about Misaki Ayuzawa, the smart, beautiful and hardworking Student Council President of Seika High School who has turn her once all-boys now co-ed school from a very dirty, indiscipline school to a clean, proper school for the girls learning there which has most of the male student populace fear her as a boy hating, head strong disciplinarian while the teachers and female student populace see her as their shining hope and hero. However, she has a dark secret that her school doesn't know as she secretly works part-time at a maid cafe in order to support her family.
Unfortunately, her secret is found out by Usui Takumi, a boy at her school who she finds annoying due to his odd attitude yet is well like by the girls at their school, due to his looks, smarts and is one of the few "good boys" of Seika High School. Despite her fears, he doesn't reveal her secret to the school but instead takes an interest of her. What follows is the growing relationship and eventually, romance between Misaki and Usui.
I really find this first ep enjoyable and look forward to the next.
I recommend anyone that enjoys english subbed anime to watch it.
Being in XviD it works streamed to an Xbox360 and PS3 also.
Its a shame the subbed one wasnt available on AU TV like SBS HD,
ohh well, thats what fansubs are for I guess.